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The shift of IR absorption peaks in the SEIRA spectra is due to interaction of the target molecule with metal nanoparticles, especially related to the orientation of target molecule on the metal surface ( 1 ) is missing in the surface-enhanced IR absorption spectrum of glutathione, which is the reaction of the silver nanoparticles with the sulfhydryl group in glutathione to form AgS bonds

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Curr Pharm Des 14(11):11131123 Frederiksen LJ, Sullivan R, Maxwell LR, Macdonald-Goodfellow SK, Adams MA, Bennett BM, Siemens DR, Graham CH (2007) Chemosensitization of cancer in vitro and in vivo by nitric oxide signaling

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Differential requirements for l-citrulline and l-arginine during antimycobacterial macrophage activity