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Although the reaction of PhSeBr and 1a generating the SeN intermediate INT1-Se is endothermic by 12.6 kcal mol 1 , INT1-Se may readily undergo a Se-centred [2,3]-sigmatropic rearrangement to generate an ortho -Se = N substituted dearomatized species ( INT2-Se ) via TS1-Se , with a barrier of 12.7 kcal mol 1

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[DOI] [PubMed] [Google Scholar] Lienqueo M., Salazar O., Calado C., Fonseca L., Cabral J

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Abstract Ethanol consumption is widely recognized for its detrimental effects on mental health, particularly its association with depressive disorders