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This occurs because: Stress diverts blood flow away from the digestive system and towards muscles and the brain to help you prepare for danger (fight or flight mode)

It starts affecting you sooner if you are well-hydrated

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Waberzinek G, Markov J, Mastik J

Step 3: tert-Butyl 4-(6-((7-cyclopentyI-6-(dimethylcarbainoyI)-7H-pyrrolof2,3- d]pyrimidin-2-y l)amino)pyridin-3-yl-2,4,5-d^iperazine- 1 -carboxylate A mixture of tert-butyl 4-(6-bromopyridin-3-yl-2,4,5-dj)piperazine-l -carboxylate (150 mg, 0.43 mmol) and 2-amino-7-cyclopentyl-N,N-dimethyl-7H-pyrrolo[2,3-d|pyrimidine- 6- carboxamide (120 mg, 0.44 mmol), Pd(dba) 2 (12.6 mg, 0.022 mmol), BINAP (20 mg, 0.032 mmol) and CS2CO3 (420 mg, 1.29 mmol) in dioxane (3 mL) is degassed and heated to 1 10 C over a period of 24 hours

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